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If this is your first bicycle project paint, then I would suggest keeping it economical and simple. I find that if I try to do too much and get in way over my head, then I'll never finish and be discouraged to build/convert another.
Try using the highest quality aerosol can primer and paint, that you can afford. Quality, I'm refering to the top brand(s) of your resident locality. Read the labels and make sure they are compatible (work together chemically) and use gloves and masks when needed to protect yourself.
Clean the bike with a clean rag then followed by a clean rag soaked in denatured alcohol because the alcohol is not as volatile as gasoline and paint solvents, although it is imflammable so do not use near open flame.
Scuff the existing paint coat with scuff pads which look like scouring pads for washing pots and pans in the kitchen. The scuff pads will take out the shine and leave a dull finish for your new coat of primer to stick to.
Wipe again with clean rag all over to remove any residue and debris from previous steps.
Prime with sandable primer from spray can then you can see flaws in privious paint where you may or may not want to putty and sand. That will be optional, remember this is your first bike and unless it's going into a show competition next month, don't worry about little stuff.
Paint with the color you chose straight out of the spray can.
hope this helps.
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